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Path: CSPS Online Home » Abstracts » 2000 Abstracts » Chapter 11
« Chapter 10B 2000 Annual Report Abstracts  
A Modified Free-Volume Model: Correlation of Ion-Conduction in Strongly Associating Polymeric Materials
Narayan Ramesh

Ions tend to aggregate in media of low dielectric constant, and this tendency to form strong associations causes small amounts of ionic functionality to have a significant influence on the properties of ionic polymers. As a consequence of ionic functionality and strong interactions ionomers exhibit unique transport characteristics compared to conventional polymers. While it has been observed that ion mobility is related to viscosity, a comprehensive theory like the existing theories for non-associating systems has not been developed for associating systems. In this study, we developed a modified free-volume approach to describe ion-diffusion and conduction is associating systems.

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