The Center has developed the unique capability
of measuring polymer solution vapor equilibria and diffusivities
at high pressures and temperatures. The applications have included
the formulation of blowing agents to be dissolved in molten
polymers during extrusion to produce polymer
foams; diffusion and distribution of co-monomers in high-pressure
polymerization reactors; and defect
formation related to the influence of pressure on the solubility
of impurities such as air and water in polymer films. The Center
has been particularly effective at predicting and correlating
solubilities of gases and liquids in polymers at high pressures
using the group-contribution based lattice-fluid equation of
state (GCLF-EoS), developed within the Center.
The Center has also developed the capability
to conduct extraction of impurities from polymers exposed to
high pressure supercritical fluids
such as carbon dioxide. A related apparatus is the remote visualization
apparatus so that defect formation such as bubbles can be observed
in polymers in situ at high pressures. |