 |
|
The utilization of supercritical fluids in
the production and processing of polymers is a unique and emerging
field. The Center has concentrated on the purification of polymers
using supercritical fluids such as carbon dioxide. When a polymer
is exposed to a supercritical fluid such as carbon dioxide,
often the supercritical fluid enters the polymer and significantly
swells it. This is even an effective method for inert polymers
such as fluoropolymers. In the swollen state, impurities in
the polymer-supercritical phase can diffuse relatively quickly
and be absorbed into the external supercritical fluid. The Center
has a patent that clearly shows that supercritical fluid extraction
can be very effective in removing impurities from glassy polymers.
In this case, there is a unique mechanism. When a supercritical
fluid such as carbon dioxide is quickly removed from the polymer
by depressurization, a meta-stable state exists in the glassy
polymer. It takes a finite amount of time for the polymer volume
to relax to its equilibrium state and during that period of
time, the impurities can be quickly removed from the polymer. |
 |